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Related Concept Videos

Aromatic Hydrocarbon Cations: Structural Overview01:18

Aromatic Hydrocarbon Cations: Structural Overview

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
Removing one hydrogen from the intervening CH2 group...
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Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Thermal and Photochemical Electrocyclic Reactions: Overview

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Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
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Olefin Metathesis Polymerization: Overview01:13

Olefin Metathesis Polymerization: Overview

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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists of a...
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Related Experiment Video

Updated: Mar 21, 2026

Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
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Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology

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Polymers with pendant ferrocenes.

Rudolf Pietschnig1

  • 1Universität Kassel, Institut für Chemie und CINSaT, Heinrich-Plett-Straße 40, 34132 Kassel, Germany. pietschnig@uni-kassel.de.

Chemical Society Reviews
|May 10, 2016
PubMed
Summary

Smart polymers with ferrocene units offer tunable properties like charge and color through redox activity. This enables applications in advanced materials and sensing technologies.

Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Electrochemistry

Background:

  • Tailoring smart material properties is a key challenge in materials science.
  • Polymers with pendant ferrocene units exhibit unique electrochemical, electronic, optoelectronic, catalytic, and biological properties.
  • These properties hold significant potential for smart material applications.

Purpose of the Study:

  • To review recent advancements (past five years) in smart materials based on ferrocene-containing polymers.
  • To highlight the role of ferrocene redox activity in tuning material properties.
  • To explore sensing applications utilizing ferrocene polymers and enzymes.

Main Methods:

  • Review of literature focusing on the past five years.
  • Analysis of polymers functionalized with ferrocenyl or ferrocenediyl groups.

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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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  • Investigation of redox switching mechanisms and their impact on material properties.

    • Main Results:

    • Ferrocene redox activity allows control over polymer charge, polarity, UV-vis color, and hydrophilicity.
    • Cooperative or individual switching of ferrocene units enables property modulation.
    • Polymer-bound enzymes can influence ferrocene redox behavior, facilitating sensing.

    Conclusions:

    • Ferrocene-containing polymers offer a versatile platform for developing smart materials.
    • The redox-switchable nature of ferrocene is central to controlling material characteristics.
    • These materials show promise for advanced applications, including chemical sensing.