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Updated: Mar 20, 2026

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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
Published on: January 17, 2020
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Microporous polyurethane material for size selective heterogeneous catalysis of the Knoevenagel reaction
Sandeep Kumar Dey1, Nader de Sousa Amadeu1, Christoph Janiak1
1Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, 40204 Düsseldorf, Germany. janiak@uni-duesseldorf.de.
Abstract:
The first polyurethane material which is microporous (BET surface area of 312 m(2) g(-1)) is prepared by solvothermal synthesis and acts as highly efficient and recyclable heterogeneous catalyst in the Knoevenagel condensation showing size selectivity, and in the Henry reaction showing substrate selectivity under mild reaction conditions.
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