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Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
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NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of one, the...
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The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved...
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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Cavity Optomagnonics with Spin-Orbit Coupled Photons.

A Osada1, R Hisatomi1, A Noguchi1

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Physical Review Letters
|June 18, 2016
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Summary
This summary is machine-generated.

We demonstrate cavity optomagnonics using ferromagnetic spheres, observing nonreciprocal light scattering due to magnon dynamics. This opens avenues for quantum optics and spintronics applications.

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Area of Science:

  • Physics
  • Quantum Optics
  • Spintronics

Background:

  • Cavity optomagnonics explores light-matter interactions mediated by magnons.
  • Whispering gallery modes (WGMs) in dielectric resonators confine photons.
  • Ferromagnetic materials host magnons, the quanta of spin waves.

Purpose of the Study:

  • To experimentally implement a cavity optomagnonic system.
  • To investigate magnon-induced Brillouin scattering of light.
  • To explore nonreciprocity and asymmetry in optical signals.

Main Methods:

  • Utilizing a ferromagnetic sphere supporting optical WGMs and magnons.
  • Analyzing sideband signals from light scattering.
  • Applying principles of spin-orbit coupling and birefringence.

Main Results:

  • Observed pronounced nonreciprocity and asymmetry in sideband signals.
  • Identified angular-momentum selection rules governing the scattering process.
  • Linked phenomena to spin-orbit coupling, geometrical birefringence, and magnon dynamics.

Conclusions:

  • The implemented system exhibits unique optical nonreciprocity.
  • Spin-orbit coupling and magnon time-reversal symmetry breaking are key.
  • Potential applications exist at the intersection of quantum optics and spintronics.