Diazonium Functionalisation of Carbon Nanotubes for Specific Orientation of Multicopper Oxidases: Controlling

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Noémie Lalaoui1,2, Michael Holzinger1,2, Alan Le Goff3,4

  • 1Univ. Grenoble Alpes, DCM UMR 5250, 38000, Grenoble, France.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|June 22, 2016
PubMed

Keywords:
bilirubin oxidasesdiazoniummetalloenzymesnanotubesoxygen reduction

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Arenediazonium substitution reactions occur when the diazonium group is substituted by various functional groups such as halides, hydroxyl, nitrile, etc. For instance, arenediazonium salts react with copper(I) salts of chloride, bromide, or cyanide to form corresponding aryl chlorides, bromides, and nitriles. These reactions are named Sandmeyer reactions. Although the mechanism of this reaction is complicated, as illustrated in Figure 1, they are believed to progress via an aryl copper...
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