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Updated: Mar 19, 2026

Electrospinning of Photocatalytic Electrodes for Dye-sensitized Solar Cells
Published on: June 28, 2017
Interfacial Charge Transfer in Dye-Sensitized Solar Cells Using SCN-Free Terpyridine-Coordinated Ru Complex Dye and
Takahiro Kono1, Naruhiko Masaki2, Masahiro Nishikawa2
1Center for Energy and Environmental Science, Shinshu University , 4-17-1 Wakasato, Nagano 380-8553, Japan.
Abstract:
The efficiency of dye-sensitized solar cells (DSSCs) using Ru complex dyes and Co complex redox couples has been increased with a strategy to prevent charge recombination via the addition of bulky or lengthy peripheral units to the dyes. However, despite the efforts, most of the DSSCs are still suffering from nonunity quantum efficiency and fast recombination. We examine the effect of SCN ligand, which has been used for many Ru complex dyes and could attract positively charged Co complexes. We find that replacing the ligands with 2,6-bis(2'-(4'-trifluoromethyl)pyrazolyl)pyridine increases the quantum efficiency and electron lifetime. With the combination of the replacement of SCN ligands and the addition of bulky moiety, ∼80% external quantum efficiency is achieved. These suggest that not only the addition of a blocking effect but also the reduction of electrostatic and dispersion forces between dyes and Co complexes are essential to control the charge separation and recombination processes.
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