Related Experiment Video
Updated: Mar 18, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Le Chatelier Principle for Out-of-Equilibrium and Boundary-Driven Systems: Application to Dynamical Phase Transitions
1Department of Physics, Technion Israel Institute of Technology, Haifa 32000, Israel.
Abstract:
A stability analysis is presented for boundary-driven and out-of-equilibrium systems in the framework of the hydrodynamic macroscopic fluctuation theory. A Hamiltonian description is proposed which allows us to thermodynamically interpret the additivity principle. A necessary and sufficient condition for the validity of the additivity principle is obtained as an extension of the Le Chatelier principle. These stability conditions result from a diagonal quadratic form obtained using the cumulant generating function. This approach allows us to provide a proof for the stability of the weakly asymmetric exclusion process and to reduce the search for stability to the solution of two coupled linear ordinary differential equations instead of nonlinear partial differential equations. Additional potential applications of these results are discussed in the realm of classical and quantum systems.
Related Concept Videos
Le Chatelier's Principle: Changing Concentration
Le Chatelier's Principle: Changing Temperature
To understand this phenomenon, consider the elementary reaction:
Le Chatelier's Principle: Changing Volume (Pressure)
The Response of Equilibria to the Conditions
Second Law of Thermodynamics
Second Law of Thermodynamics

