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Spontaneous wettability patterning via creasing instability.

Dayong Chen1, Gareth H McKinley2, Robert E Cohen3

  • 1Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139; Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139.

Proceedings of the National Academy of Sciences of the United States of America
|July 7, 2016
PubMed
Summary
This summary is machine-generated.

Researchers developed a simple dip-coating method to create patterned wettability surfaces on elastomers. This technique allows for spontaneous pattern generation on both flat and curved surfaces, offering a scalable alternative to traditional microfabrication for applications like heat transfer and water collection.

Keywords:
creasing instabilitycurved surfacesdomain sizemorphologywettability contrast

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Area of Science:

  • Materials Science
  • Surface Science
  • Polymer Science

Background:

  • Patterned wettability surfaces are crucial for industrial applications including heat transfer, water collection, and particle separation.
  • Conventional fabrication methods like microfabrication have limitations in scalability and applicability to curved substrates.

Purpose of the Study:

  • To develop a scalable and versatile method for creating wettability patterns on both flat and curved surfaces.
  • To explore the use of mechanical instability in polyurethane elastomer films for spontaneous pattern generation.

Main Methods:

  • Utilizing a mechanical instability inherent in polyurethane elastomer films.
  • Employing a simple dip coating process for surface fabrication.
  • Controlling pattern characteristics through variations in dipping time, sample prestress, and chemical treatment.

Main Results:

  • Successfully generated spontaneous wettability patterns on polyurethane elastomer surfaces.
  • Achieved independent control over domain size (100–500 μm), morphology, and wettability contrast.
  • Demonstrated applicability to both flat and curved surfaces.

Conclusions:

  • The dip coating method offers a facile and scalable approach to fabricating patterned wettability surfaces.
  • This technique overcomes limitations of traditional microfabrication, enabling applications on complex geometries.
  • The ability to tune pattern characteristics provides flexibility for diverse industrial needs.