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Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
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The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
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Surface-atmosphere decoupling limits accumulation at Summit, Greenland.

Max Berkelhammer1, David C Noone2, Hans Christian Steen-Larsen3

  • 1Department of Earth and Environmental Sciences, University of Illinois at Chicago, Chicago, IL 60607, USA.; Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA.; Department of Atmospheric and Oceanic Sciences, University of Colorado, Boulder, CO 80309, USA.

Science Advances
|July 8, 2016
PubMed
Summary
This summary is machine-generated.

Greenland Ice Sheet's interior accumulation is not solely controlled by temperature. Stable atmospheric conditions create a decoupling, recycling moisture and conserving ice mass through fog formation.

Keywords:
Greenland Ice sheetatmospheric boundary layerclimate changeice-atmosphere interactionpolar climatewater isotopes

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Area of Science:

  • Glaciology
  • Atmospheric Science
  • Isotope Hydrology

Background:

  • Coastal Greenland Ice Sheet regions experience rapid melting, but ~40% of the interior rarely melts.
  • Surface conditions like clouds and inversions create uncertainty in estimating moisture flux and accumulation in the ice sheet interior.
  • Existing models suggest accumulation is thermodynamically controlled by temperature-dependent vapor pressure, but ice core data show variability.

Purpose of the Study:

  • To investigate the mechanisms controlling annual accumulation in the rarely melting interior of the Greenland Ice Sheet.
  • To assess the role of atmospheric stability and surface-atmosphere interactions in regulating moisture flux and ice mass balance.
  • To understand the implications for interpreting past climate records from ice cores.

Main Methods:

  • Analysis of three years of stable water vapor isotope profiles from a high-altitude Greenland Ice Sheet site.
  • Investigating the relationship between atmospheric boundary layer stability and moisture transport.
  • Utilizing isotopic signatures to trace moisture pathways and recycling processes.

Main Results:

  • Increasing atmospheric boundary layer stability leads to decoupling between the ice sheet surface and the free troposphere.
  • This decoupling limits surface condensation, reducing moisture flux to rates below thermodynamic potential.
  • A mechanism of moisture recycling via fog formation and gravitational settling conserves ice sheet mass.

Conclusions:

  • Ice sheet mass conservation in the interior is influenced by a unique atmospheric decoupling and moisture recycling mechanism, not just thermodynamics.
  • This finding challenges purely thermodynamic controls on accumulation and has significant implications for paleoclimate reconstructions using ice core isotopes.
  • Understanding these processes is crucial for accurately predicting future changes in Greenland Ice Sheet mass balance.