A Method for the Efficient Fabrication of Multifunctional Mosaic Membranes by Inkjet Printing

Most conventional membrane systems are based on size-selective materials that permeate smaller molecules and retain larger ones. However, membranes that can permeate larger molecules more rapidly than smaller ones could find widespread utilization in multiple arenas of technology. Charge mosaic membranes are one example of such a system. Due to their unique nanostructure, which consists of discrete oppositely charged domains, charge mosaics are capable of permeating large dissolved salts more rapidly than smaller water molecules. Here, we present a combined inkjet printing and template synthesis technique to prepare charge mosaic membranes in a rapid and straightforward manner and demonstrate the unique transport properties that result from the mosaic membrane design. Poly(vinyl alcohol)-based composite inks containing poly(diallyldimethylammonium chloride) or poly(sodium 4-styrenesulfonate) were used to pattern positively charged or negatively charged domains, respectively, on the surface of a polycarbonate track-etched membrane with 30 nm pores. The ability to control the net surface charge of the mosaic membranes through the rational deposition of oppositely charged materials was demonstrated and confirmed through nanostructural characterization, electrokinetic measurements, and piezodialysis experiments. Namely, mosaic membranes that possessed an overall neutral charge (i.e., membranes that had equal coverage of positively and negatively charged domains) were capable of enriching the concentration of potassium chloride in the solution that permeated through the membrane. These membranes can be deployed in the many established and emerging nanoscale technologies that rely on the selective transport and separation of ionic solutes from solution. Furthermore, because of the flexibility provided by the membrane fabrication platform, the efforts reported in this work can be extended to other mosaic designs with myriad other functional components.