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IR Absorption Frequency: Hybridization01:21

IR Absorption Frequency: Hybridization

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Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that...
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Writing Bragg Gratings in Multicore Fibers
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Waveguide Bragg gratings in Ormocer hybrid polymers.

Maiko Girschikofsky, Michael Förthner, Mathias Rommel

    Optics Express
    |July 14, 2016
    PubMed
    Summary

    Researchers fabricated Bragg gratings in Ormocer hybrid polymer waveguides using deep-UV laser radiation. This method achieved high reflectivity (up to 98%) and narrow bandwidths (down to 120 pm) for optical applications.

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    Area of Science:

    • Materials Science
    • Optoelectronics
    • Photonics

    Background:

    • Inorganic-organic hybrid polymers (Ormocers) offer tunable optical properties.
    • Waveguide Bragg gratings are crucial components in integrated photonic circuits.
    • Efficient fabrication methods for high-performance gratings are needed.

    Purpose of the Study:

    • To report the fabrication of Bragg gratings in Ormocer rib-type waveguides.
    • To investigate the influence of laser fluence and grating length on grating characteristics.
    • To compare experimental results with numerical simulations.

    Main Methods:

    • Interferometric phase mask technique combined with deep-UV laser radiation.
    • Fabrication of Bragg gratings within rib-type waveguides.
    • Characterization of transmission and reflection spectra.

    Main Results:

    • Successfully fabricated waveguide Bragg gratings in UV-cured Ormocer.
    • Achieved high reflectivities up to 98%.
    • Obtained narrow bandwidths down to 120 pm, dependent on laser fluence and grating length.

    Conclusions:

    • The interferometric phase mask technique is effective for creating high-performance Bragg gratings in Ormocer waveguides.
    • Optimized laser fluence and grating length are key to achieving desired spectral characteristics.
    • This fabrication method holds promise for advanced integrated photonic devices.