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Updated: Mar 17, 2026

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On the fractality of the Freundlich adsorption isotherm in equilibrium and non-equilibrium cases
Przemysław Borys1, Zbigniew J Grzywna1
1ks. M. Strzody 9, 44-100 Gliwice, Poland. Przemyslaw.Borys@polsl.pl.
Abstract:
We investigate the relationship between the Freundlich adsorption exponent and the fractal dimension of the adsorption sites for quasi-monolayer adsorption, and of the adsorbed aggregate for a simple case of multilayer adsorption. We further check whether the Freundlich adsorption mechanism may contribute to anomalous diffusion in the transport through porous materials.
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To understand this phenomenon, consider the elementary reaction: