Related Experiment Video
Updated: Mar 17, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Distributional behaviors of time-averaged observables in the Langevin equation with fluctuating diffusivity: Normal
Takuma Akimoto1, Eiji Yamamoto1
1Department of Mechanical Engineering, Keio University, Yokohama 223-8522, Japan.
Abstract:
We consider the Langevin equation with dichotomously fluctuating diffusivity, where the diffusion coefficient changes dichotomously over time, in order to study fluctuations of time-averaged observables in temporally heterogeneous diffusion processes. We find that the time-averaged mean-square displacement (TMSD) can be represented by the occupation time of a state in the asymptotic limit of the measurement time and hence occupation time statistics is a powerful tool for calculating the TMSD in the model. We show that the TMSD increases linearly with time (normal diffusion) but the time-averaged diffusion coefficients are intrinsically random when the mean sojourn time for one of the states diverges, i.e., intrinsic nonequilibrium processes. Thus, we find that temporally heterogeneous environments provide anomalous fluctuations of time-averaged diffusivity, which have relevance to large fluctuations of the diffusion coefficients obtained by single-particle-tracking trajectories in experiments.
Related Concept Videos
Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion
Mean free path and Mean free time
The Integrated Rate Law: The Dependence of Concentration on Time
Distribution of Molecular Speeds
Reynolds Transport Theorem
Entropy

