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Unusual alkaloids of the highland species Astragalus cryptanthus Wedd. (Fabaceae)
Javier Echeverría1, Sergio M Espinoza1, Hermann M Niemeyer1
1a Laboratorio de Química Ecológica, Facultad de Ciencias, Departamento de Ciencias Ecológicas , Universidad de Chile , Santiago , Chile.
Abstract:
Two unusual caprolactam alkaloids, 3-(dimethylamino)hexahydro-2H-azepin-2-one and 3-(methylamino)-hexahydro-2H-azepin-2-one, were isolated from the aerial parts of Astragalus cryptanthus Wedd.; their structures were unambiguously determined based on data from extensive 1D and 2D NMR, GC-MS and FT-IR spectroscopic analyses. This is the first report of this alkaloid type in the genus Astragalus.
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