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Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles
Published on: March 2, 2016
Hybridized plasmon modes and near-field enhancement of metallic nanoparticle-dimer on a mirror
Yu Huang1, Lingwei Ma1, Mengjing Hou1
1State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, P. R. China.
Abstract:
For the attractive plasmonic structure consisting of metal nanoparticles (NPs) on a mirror, the coexistence of near-field NP-NP and NP-mirror couplings is numerically studied at normal incidence. By mapping their 3D surface charge distributions directly, we have demonstrated two different kinds of mirror-induced bonding dipole plasmon modes and confirmed the bonding hybridizations of the mirror and the NP-dimer which may offer a much stronger near-field enhancement than that of the isolated NP dimers over a broad wavelength range. Further, it is revealed that the huge near-field enhancement of these two modes exhibit different dependence on the NP-NP and NP-mirror hot spots, while both of their near-field resonance wavelengths can be tuned to the blue exponentially by increasing the NP-NP gaps or the NP-mirror separation. Our results here benifit significantly the fundamental understanding and practical applications of metallic NPs on a mirror in plasmonics.

