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Updated: Mar 17, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Chiral, triformylphenol-derived salen-type [4 + 6] organic cages
M Petryk1, J Szymkowiak, B Gierczyk
1Department of Chemistry, Adam Mickiewicz University, Umultowska 89B, 61 614 Poznań, Poland. agnieszk@amu.edu.pl marcin.kwit@amu.edu.pl.
Abstract:
A one-pot synthesis of chiral [4 + 6] tetrahedral cage compounds containing a salen fragment on each face is presented. The formation of the [4 + 6] products remains in contrast to the reaction of 1,3,5-triformylphloroglucinol with chiral diamines where [2 + 3] keto-enamine pseudocyclophanes are formed exclusively. The presence of OH groups determines the structural and spectroscopic properties of these cage compounds while a change in the reaction conditions facilitates the isolation of the microcrystalline products of the specific surface area varying from 5 to 578 m(2) g(-1).
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