Review of soluble uranium removal by nanoscale zero valent iron

Uranium (U) has been released to surface soil and groundwater through military and industrial activities. Soluble forms of U transferred to drinking water sources and food supplements can potentially threaten humans and the biosphere due to its chemical toxicity and radioactivity. The immobilization of aqueous U onto iron-based minerals is one of the most vital geochemical processes controlling the transport of U. As a consequence, much research has been focused on the use of iron-based materials for the treatment of U contaminated waters. One material currently being tested is nanoscale zero-valent iron (nZVI). However, understanding the removal mechanism of U onto nZVI is crucial to develop new technologies for contaminated water resources. This review article aims to provide information on the removal mechanism of U onto nZVI under different conditions (pH, U concentration, solution ion strength, humic acid, presence of O₂ and CO₂, microorganism effect) pertinent to environmental and engineered systems, and to provide risk or performance assessment results with the stability of nZVI products after removal of U in environmental restoration.