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Extended conjugated microporous polymers for photocatalytic hydrogen evolution from water
Reiner Sebastian Sprick1, Baltasar Bonillo1, Michael Sachs2
1Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool, L69 7ZD, UK. aicooper@liverpool.ac.uk.
Abstract:
Conjugated microporous polymers (CMPs) have been used as photocatalysts for hydrogen production from water in the presence of a sacrificial electron donor. The relative importance of the linker geometry, the co-monomer linker length, and the degree of planarisation were studied with respect to the photocatalytic hydrogen evolution rate.
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