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Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates
Furong Guo1, Cheng Chen1, Kangcai Wang2
1College of Chemistry, Sichuan University , Chengdu 610064, P. R. China.
Inorganic Chemistry
|July 26, 2016
Abstract:
A series of open-framework metal oxalates (metal = Zn, Co, Mn, Bi, In) were prepared under solvent-free conditions by a supramolecular templating approach. These compounds have cationic, anionic, and neutral frameworks with pore apertures ranging from small 8-membered rings (8 MRs) to extra-large 16 and 20 MRs. The zinc oxalate exhibits a proton conductivity of 2.6 × 10(-3) S cm(-1) at 60 °C under 98% relative humidity.
