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Self-forming TiBN Nanocomposite Multilayer Coating Prepared by Pulse Cathode Arc Method.
Yongzhi Cao1, Zhenjiang Hu2, Leilei Yan2
1Center for Precision Engineering, Harbin Institute of Technology, Harbin, 150001, People's Republic of China. cflying@hit.edu.cn.
Nanoscale Research Letters
|July 28, 2016
Summary
Novel titanium boron nitride (TiBN) coatings exhibit a self-forming multilayer structure. The inclusion of hexagonal boron nitride (BN) significantly reduces friction compared to titanium nitride (TiN) coatings.
Area of Science:
- Materials Science
- Nanotechnology
- Tribology
Background:
- Titanium nitride (TiN) coatings are widely used due to their hardness and wear resistance.
- Developing advanced coatings with enhanced tribological properties remains a key research area.
- Multilayer structures can offer synergistic improvements in material performance.
Purpose of the Study:
- To synthesize and characterize novel multilayer TiBN coatings.
- To investigate the structural properties of the TiBN coatings.
- To evaluate the tribological performance, specifically friction, of the TiBN coatings.
Main Methods:
- Deposition of TiBN coatings on Si (100) substrates using Plasma Immersion Ion Implantation and Deposition (PIIID).
- Characterization using X-ray Diffraction (XRD), High-Resolution Transmission Electron Microscopy (HRTEM), and Energy-Dispersive Spectrometry (EDS).
- Tribological testing via a ball-on-disk test to determine friction coefficient.
Main Results:
- XRD confirmed the presence of TiN (200) and (220) diffraction peaks in the TiBN coatings.
- HRTEM revealed a self-forming multilayer structure with face-centered cubic TiN and hexagonal BN nanocrystals embedded in an amorphous matrix.
- The TiBN coatings exhibited a significantly lower friction coefficient at room temperature compared to monolithic TiN coatings.
Conclusions:
- The PIIID technique successfully produced novel multilayer TiBN coatings.
- The incorporation of hexagonal BN within the multilayer structure is crucial for reducing friction.
- These TiBN coatings show promise for applications requiring low friction and wear resistance.

