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Two Components: Liquid–Liquid Systems01:27

Two Components: Liquid–Liquid Systems

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A pressure-composition phase diagram explicitly describes the behavior of an ideal solution of two volatile liquids under varying pressures and compositions. A pressure-composition diagram has two main curves. The bubble point curve represents the plot of pressure versus liquid mole fraction. It indicates the pressure at which the first bubble of vapor forms from the liquid phase as the system pressure decreases.The dew point curve is the pressure versus vapor mole fraction. It indicates the...
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Liquid–Solid Solutions01:29

Liquid–Solid Solutions

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The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...
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Nonideal Two-Component Liquid Solutions01:29

Nonideal Two-Component Liquid Solutions

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Nonideal liquid solutions, also known as real solutions, do not strictly follow Raoult's law. Raoult's law is a rule of thumb in physical chemistry. However, not all mixtures adhere to this law due to varying molecular interactions. For example, in an acetone/chloroform solution, the individual vapor pressures of the components are lower than expected, resulting in a total vapor pressure below that predicted by Raoult's law, causing a negative deviation.On the other hand, in an ethanol/water...
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Network Covalent Solids02:18

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Hydrogen Bonds01:04

Hydrogen Bonds

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A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
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The Fluid Mosaic Model01:34

The Fluid Mosaic Model

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The fluid mosaic model was first proposed as a visual representation of research observations. The model comprises the composition and dynamics of membranes and serves as a foundation for future membrane-related studies. The model depicts the structure of the plasma membrane with a variety of components, which include phospholipids, proteins, and carbohydrates. These integral molecules are loosely bound, defining the cell’s border and providing fluidity for optimal function.
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Updated: Mar 17, 2026

Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites
12:21

Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites

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Hydrogen-Bonded Liquid Crystal Nanocomposites.

Mahdi Roohnikan1,2, Violeta Toader1, Alejandro Rey2

  • 1Department of Chemistry, Centre for Self-Assembled Chemical Structures (CSACS) , 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.

Langmuir : the ACS Journal of Surfaces and Colloids
|July 29, 2016
PubMed
Summary

Functionalizing zirconium dioxide nanoparticles (ZrO2 NPs) with phosphonic acid ligands improves their miscibility in liquid crystal (LC) matrices. This controlled interaction enhances the properties of nanoparticle-liquid crystal composites.

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Physical Chemistry

Background:

  • Nanoparticle-liquid crystal (NP-LC) composites offer tunable properties for advanced applications.
  • Controlling nanoparticle-ligand interactions is crucial for achieving desired composite characteristics.
  • Zirconium dioxide nanoparticles (ZrO2 NPs) present unique surface chemistry for functionalization.

Purpose of the Study:

  • To explore nanoparticle-liquid crystal (NP-LC) composites using hydrogen bonding interactions.
  • To investigate the effect of varying ligand shells on zirconium dioxide nanoparticles (ZrO2 NPs) and their interaction with 4-n-hexylbenzoic acid (6BA).
  • To characterize the miscibility and impact of NPs on the nematic order in LC matrices.

Main Methods:

  • Synthesis and functionalization of 3 nm diameter ZrO2 NPs with varying ligand shells.
  • Characterization of NP-LC composites using polarized optical microscopy (POM), fluorescence microscopy, and 2H NMR spectroscopy.
  • Analysis of miscibility and nematic order as a function of NP concentration.

Main Results:

  • Nonfunctionalized ZrO2 NPs exhibited poor miscibility and strong disruption of the LC matrix due to irreversible binding.
  • Functionalization with phosphonic acid ligands (6PHA, 6BPHA) improved miscibility by enabling selective binding to the NP surface.
  • Addition of spacer groups (HPA) further controlled miscibility by tuning pendant CO2H group concentration.
  • Functionalized NPs showed no aggregation in the nematic phase below critical concentrations and concentrated in LC defects.

Conclusions:

  • Ligand design is critical for controlling the miscibility and self-assembly of ZrO2 NPs in LC systems.
  • Phosphonic acid functionalization offers a viable strategy for creating stable and well-dispersed NP-LC composites.
  • The findings provide insights into designing advanced NP-LC materials with tailored properties.