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Updated: Mar 17, 2026

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
Hydrogen peroxide activation by fluorophilic polyoxotungstates for fast and selective oxygen transfer catalysis
Mauro Carraro1, Martino Gardan, Andrea Sartorel
1ITM-CNR and Department of Chemical Sciences, University of Padova, via Marzolo 1, 35131 Padova, Italy. mauro.carraro@unipd.it marcella.bonchio@unipd.it.
Abstract:
Fluorophilic polyoxotungstates perform the selective epoxidations of internal and terminal double bonds by hydrogen peroxide (H2O2) activation in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), under mild temperature conditions. A hybrid synergy of supramolecular interactions, involving the inorganic cluster and the fluorinated solvent, is envisaged to boost H2O2 activation and the oxygen transfer mechanism. 1,2-Epoxides have been obtained with >99% selectivity and 98% yield at T = 40-70 °C.
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