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Biodegradability and plasticizing effect of yerba mate extract on cassava starch edible films
Carolina Medina Jaramillo1, Tomy J Gutiérrez2, Silvia Goyanes3
1LPMC, Dep. Física, IFIBA-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria (1428), Pab. 1, Buenos Aires, Argentina; Instituto de Tecnología en Polímeros y Nanotecnología ITPN, UBA-CONICET, Facultad de Ingeniería, Universidad de Buenos Aires, Av. Las Heras 2214 (1127), Buenos Aires, Argentina.
Abstract:
Biodegradable and edible cassava starch-glycerol based films with different concentrations of yerba mate extract (0, 5 and 20wt.%) were prepared by casting. The plasticizing effect of yerba mate extract when it was incorporated into the matrix as an antioxidant was investigated. Thermal degradation and biodegradability of the obtained biofilms were also studied. Thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), attenuated total reflectance Fourier transform infrared spectroscopy (ATR/FTIR), X-ray diffraction analysis (XRD), water absorbance, stability in different solutions and biodegradability studies were performed. The clear correlation among the results obtained from the different analysis confirmed the plasticizing effect of yerba mate extract on the starch-glycerol matrix. Also, the extract led to a decrease in the degradation time of the films in soil ensuring their complete biodegradability before two weeks and to films stability in acidic and alkaline media. The plasticizing effect of yerba mate extract makes it an attractive additive for starch films which will be used as packaging or coating; and its contribution to an earlier biodegradability will contribute to waste reduction.

