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Updated: Mar 16, 2026

Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
Published on: July 9, 2015
A bentonite-gold nanohybrid as a heterogeneous green catalyst for selective oxidation of silanes
R J Maya1, Jubi John2, R Luxmi Varma1
1Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India. lux_varma@rediffmail.com and Organic Chemistry Section, CSIR-National Institute for Interdisciplinary Science and Technology, Thiruvananthapuram 695019, India.
Abstract:
A highly efficient, environmentally benign and reusable heterogeneous bentonite-gold nanohybrid catalyst was designed and synthesized. This heterogeneous catalyst could efficaciously catalyse the oxidation of organosilanes to silanols. The reaction is 98.7% atom economical and the products were obtained in excellent yield without the formation of disiloxanes as byproducts. The catalyst was also well applicable for the gram scale preparation of silanols.
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