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Characterization of Synthetic Polymers via Matrix Assisted Laser Desorption Ionization Time of Flight MALDI-TOF Mass Spectrometry
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Matrix-assisted laser desorption/ionization-collision induced dissociation of poly(styrene)

A T Jackson1, H T Yates2, J H Scrivens2

  • 1ICI Research and Technology Centre, Room D115, PO Box 90, TS90 8JE, Wilton, Middlesbrough, Cleveland, UK. tony_jackson@ici.com.

Journal of the American Society for Mass Spectrometry
|August 13, 2016
PubMed
Summary

Matrix-assisted laser desorption/ionization-collision induced dissociation (MALDI-CID) successfully analyzed poly(styrene) using copper and silver ion adducts. This technique infers polymer end-group masses from fragment ion peaks, revealing formation mechanisms.

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