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Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
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Ground-State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field

Anoop Thomas1, Jino George1, Atef Shalabney2

  • 1University of Strasbourg, CNRS, ISIS & icFRC, 8 allée G. Monge, 67000, Strasbourg, France.

Angewandte Chemie (International Ed. in English)
|August 17, 2016
PubMed
Summary

Chemical reactions can be controlled by vibrational strong coupling, slowing down alkynylsilane deprotection. This method modifies reaction pathways and offers insights into reaction mechanisms.

Keywords:
IR spectroscopykineticsstrong couplingthermodynamicsvibrations

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