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Updated: Mar 16, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Asymmetric dimerization of aniline-ruthenium-dioxolene complex driven by stepwise PCET.

T Kikuchi1, K Kobayashi, K Tsuge

  • 1Institute for Integrated Cell-Material Sciences, Kyoto University, 105 Jibu-cho, Fushimi-ku, Kyoto 612-8374, ACT Kyoto #507, Japan. koji.tanaka@icems.kyoto-u.ac.jp.

Dalton Transactions (Cambridge, England : 2003)
|August 19, 2016
PubMed
Summary

Base-assisted oxidation of an aniline-ruthenium-quinone complex generates an anilinyl radical-ruthenium-semiquinone. Further oxidation leads to selective intermolecular C-N bond formation via coupling at the anilinyl ligand

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