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Photoredox Catalysis in Nickel-Catalyzed Cross-Coupling
Livia N Cavalcanti1, Gary A Molander2
1Instituto de Química-Universidade Federal do Rio Grande do Norte, Natal, RN, Brazil.
Abstract:
The traditional transition metal-catalyzed cross-coupling reaction, although well suited for C(sp2)-C(sp2) cross-coupling, has proven less amenable toward coupling of C(sp3)-hybridized centers, particularly using functional group tolerant reagents and reaction conditions. The development of photoredox/Ni dual catalytic methods for cross-coupling has opened new vistas for the construction of carbon-carbon bonds at C(sp3)-hybridized centers. In this chapter, a general outline of the features of such processes is detailed.
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