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Controlled formation of ordered coordination polymeric networks using silsesquioxane building blocks
Subhabrata Banerjee1, Sho Kataoka1, Toshikazu Takahashi1
1National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. s-kataoka@aist.go.jp endo-akira@aist.go.jp.
Dalton Transactions (Cambridge, England : 2003)
|September 8, 2016
Abstract:
In this report, we synthesized ordered coordination polymers using polyhedral oligomeric silsesquioxanes (POSS) as a building block. A POSS with eight carboxylic terminals was coordinated with copper ions at various temperatures, forming polymeric networks. This novel coordination polymer has a long-range ordered structure.
