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Updated: Mar 15, 2026

Fabrication of Three-Dimensional Graphene-Based Polyhedrons via Origami-Like Self-Folding
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Tunable Optical Transparency in Self-Assembled Three-Dimensional Polyhedral Graphene Oxide.

Daeha Joung1, Tingyi Gu2, Jeong-Hyun Cho1

  • 1Department of Electrical and Computer Engineering, University of Minnesota , Minneapolis, Minnesota 55455, United States.

ACS Nano
|September 13, 2016
PubMed
Summary

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Origami-inspired self-folding creates 3D graphene oxide structures. These 3D graphene oxide polyhedrons exhibit unique optical switching properties not seen in 2D sheets.

Area of Science:

  • Materials Science
  • Nanotechnology
  • Physical Chemistry

Background:

  • Graphene oxide (GO) is a versatile material with applications in various fields.
  • Fabricating 3D GO structures presents challenges in precise control over geometry and properties.
  • 2D GO sheets have limitations in exhibiting complex optical behaviors.

Purpose of the Study:

  • To develop a novel method for creating free-standing 3D polyhedral graphene oxide structures.
  • To investigate the unique optical switching behavior of these 3D GO structures.
  • To explore the relationship between the 3D geometry and optical properties.

Main Methods:

  • Utilizing an origami-like self-folding technique for GO membrane assembly.
  • Controlling the size, shape, and thickness of GO membranes during fabrication.
Keywords:
2D materials3D microstructuregraphene oxideorigamiself-assembly

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  • Characterizing the optical properties of the resulting 3D polyhedral GO structures.
  • Main Results:

    • Successfully fabricated free-standing 3D microscale polyhedral GO structures with controlled dimensions.
    • Observed distinct optical switching behavior in 3D GO structures, differing from 2D GO sheets.
    • Attributed the optical switching to the interplay between the hollow 3D geometry and the water-permeable GO membrane.

    Conclusions:

    • The origami-like self-folding is an effective method for fabricating complex 3D graphene oxide architectures.
    • 3D polyhedral GO structures exhibit unique optical switching properties due to their unique geometry and material composition.
    • This work opens possibilities for novel optical devices and functional materials based on 3D GO structures.