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Fluctuating systems under cyclic perturbations: Relation between energy dissipation and intrinsic relaxation
Fabrizio Camerin1, Diego Frezzato1
1Department of Chemical Sciences, University of Padova, via Marzolo 1, I-35131, Padova, Italy.
This study presents an analytic approximation for energy dissipation in fluctuating classical systems undergoing cyclic transformations. The method connects average dissipation to system fluctuation rates and perturbation characteristics, aiding in spectroscopic calorimetry and system optimization.
Area of Science:
- Statistical Mechanics
- Non-equilibrium Thermodynamics
- Computational Physics
Background:
- Fluctuating classical systems interact with thermal baths, undergoing cyclic transformations driven by external perturbations.
- Understanding energy dissipation and entropy production in such systems is crucial for non-equilibrium statistical mechanics.
Purpose of the Study:
- To derive an analytic approximation for average energy dissipation per cycle in fluctuating systems.
- To connect this dissipation to the system's intrinsic fluctuation rates and perturbation properties.
- To explore applications in spectroscopic calorimetry and system optimization.
Main Methods:
- Derivation of an analytic approximation for average dissipated energy in the asymptotic limit.
- Stochastic Markov process modeling in the overdamped regime.
- Validation through stochastic simulations of a "particle on a ring" model.
Main Results:
- An accurate analytic approximation for average energy dissipation per cycle was developed.
- The approximation links dissipation to system fluctuation rates, perturbation period, and energy perturbation modes.
- The study validates the approximation against exact simulation results for a bistable potential model.
Conclusions:
- The derived approximation provides a tool to analyze energy dissipation in driven fluctuating systems.
- It enables the characterization of system dynamics and perturbation effects, akin to spectroscopic calorimetry.
- The results can guide strategies for optimizing system features based on desired energy dissipation levels.
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