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Pressure-Tuned Exchange Coupling of a Quantum Spin Liquid in the Molecular Triangular Lattice
Yasuhiro Shimizu1, Takaaki Hiramatsu2, Mitsuhiko Maesato3
1Department of Physics, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
Abstract:
The effects of pressure on a quantum spin liquid are investigated in an organic Mott insulator κ-(ET)_{2}Ag_{2}(CN)_{3} with a spin-1/2 triangular lattice. The application of negative chemical pressure to κ-(ET)_{2}Cu_{2}(CN)_{3}, which is a well-known sister Mott insulator, allows for extensive tuning of antiferromagnetic exchange coupling, with J/k_{B}=175-310 K, under hydrostatic pressure. Based on ^{13}C nuclear magnetic resonance measurements under pressure, we uncover universal scaling in the static and dynamic spin susceptibilities down to low temperatures ∼0.1k_{B}T/J. The persistent fluctuations and residual specific heat coefficient are consistent with the presence of gapless low-lying excitations. Our results thus demonstrate the fundamental finite-temperature properties of a quantum spin liquid in a wide parameter range.
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