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Preparation of Graphene Liquid Cells for the Observation of Lithium-ion Battery Material
Published on: February 5, 2019
Three-Dimensional Porous Graphene Aerogel Cathode with High Sulfur Loading and Embedded TiO2 Nanoparticles for
Jian-Qiu Huang1, Zhenyu Wang1, Zheng-Long Xu1
1Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology , Clear Water Bay, Kowloon, Hong Kong People's Republic of China.
Abstract:
Three-dimensional graphene aerogel/TiO2/sulfur (GA/TiO2/S) composites are synthesized through a facile, one-pot hydrothermal route as the cathode for lithium-sulfur batteries. With a high sulfur content of 75.1 wt %, the conductive, highly porous composite electrode delivers a high discharge capacity of 512 mA h/g after 250 cycles at a current rate of 1 C with a low capacity decay of 0.128% per cycle. The excellent capacities and cyclic stability arise from several unique functional features of the cathode. (i) The conductive graphene aerogel framework ameliorates ion/electron transfer while accommodating the volume expansion induced during discharge, and (ii) TiO2 nanoparticles play an important role in restricting the dissolution of polysulfides by chemical bonds with sulfur.

