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Formate adsorption on Pt nanoparticles during formic acid electro-oxidation: insights from in situ infrared

Ian J McPherson1, Philip A Ash1, Robert M J Jacobs2

  • 1Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, UK. kylie.vincent@chem.ox.ac.uk.

Chemical Communications (Cambridge, England)
|October 11, 2016
PubMed

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Adsorption Isotherms I01:29

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Adsorption isotherms are mathematical models that describe how molecules in a gas or liquid phase interact with surfaces. Two of the most common isotherm models are the Langmuir and Freundlich isotherms, which relate to Type I monolayer chemisorption. The Langmuir model is based on four key assumptions:• Adsorption cannot exceed monolayer coverage.• All surface sites are equivalent.• Molecules adsorb only at vacant sites.• There are no interactions between adsorbed...
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