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Stability of metal-organic frameworks under gamma irradiation

C Volkringer1, C Falaise2, P Devaux2

  • 1Unité de Catalyse et Chimie du Solide (UCCS) - UMR CNRS 8181, Université de Lille, ENSCL, Bat C7, BP 90108, 59652 Villeneuve d'Ascq, France. Christophe.volkringer@ensc-lille.fr and Institut Universitaire de France, 1 rue Descartes, 75231 Paris Cedex 05, France.

Chemical Communications (Cambridge, England)
|October 11, 2016
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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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