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Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
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Adsorption of Metallocenes on Silica

Kyle J Cluff1, Janet Blümel2

  • 1Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX, 77842-3012, USA.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|October 11, 2016
PubMed
Summary

This study demonstrates solvent-free adsorption of metallocenes onto silica gel, revealing fast molecular reorientation via solid-state NMR. This method allows for the determination of adsorption strengths and catalytic activity of supported metallocenes.

Keywords:
NMR spectroscopyadsorptioncyclotrimerizationmetallocenesnickel catalysts

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