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Stabilization of mercury over Mn-based oxides: Speciation and reactivity by temperature programmed desorption
Haomiao Xu1, Yongpeng Ma2, Wenjun Huang1
1School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Abstract:
Mercury temperature-programmed desorption (Hg-TPD) method was employed to clarify mercury species over Mn-based oxides. The elemental mercury (Hg0) removal mechanism over MnOx was ascribed to chemical-adsorption. HgO was the primary mercury chemical compound adsorbed on the surface of MnOx. Rare earth element (Ce), main group element (Sn) and transition metal elements (Zr and Fe) were chosen for the modification of MnOx. Hg-TPD results indicated that the binding strength of mercury on these binary oxides followed the order of Sn-MnOx
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