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Published on: April 27, 2019
Carbonization with Misfusion: Fundamental Limits of Carbon-Fiber Strength Revisited
Nitant Gupta1, Vasilii I Artyukhov1, Evgeni S Penev1
1Department of Materials Science and NanoEngineering, Rice University, Houston, TX, 77005, USA.
Abstract:
D-loops, a new type of structural defect in carbon fibers, are presented, which have highly detrimental effect on their mechanical properties and can define a new fundamental upper limit to their strength. These defects form exclusively during polyacrylonitrile carbonization, act as stress concentrators in the graphitic basal plane, and cannot be removed by local annealing.
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