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Aldehyde methacrylates derived from hydroxybenzaldehydes.

J M Antonucci

    Journal of Dental Research
    |March 1, 1978
    PubMed
    Summary
    This summary is machine-generated.

    New aldehyde methacrylates were synthesized and found to be low melting, polymerizable liquids. These novel monomers show promise for improving adhesion in dental resins and for proteinaceous substrates.

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    Area of Science:

    • Polymer Chemistry
    • Materials Science
    • Biomaterials

    Background:

    • Dental resins require improved adhesion to tooth structure.
    • Developing new monomers is crucial for advancing dental restorative materials.

    Purpose of the Study:

    • To synthesize and characterize novel aldehyde methacrylates.
    • To evaluate their potential as adhesion-promoting agents for dental applications.

    Main Methods:

    • Synthesis of three crystalline aldehyde methacrylates from hydroxybenzaldehydes and 2-bromoethyl methacrylate.
    • Purification by recrystallization and liquefaction by admixture.
    • Assessment of miscibility and copolymerization with dental monomers.

    Main Results:

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  • Synthesized monomers possess low melting points and workable viscosities at room temperature.
  • Monomers are miscible and copolymerizable with common dental monomers.
  • Potential for synergistic adhesion promotion with other functional methacrylates.

    • Conclusions:

    • Aldehyde methacrylates offer a new class of monomers for dental materials.
    • These monomers and their polymers/copolymers warrant investigation for enhanced adhesion to dentin and bone.