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Published on: October 5, 2019
Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal
Rong-Jia Wei1, Ryohei Nakahara1, Jamie M Cameron1
1Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. oshio@chem.tsukuba.ac.jp.
Abstract:
A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.
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