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The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
1Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, P.R. China.
Abstract:
In a multi-component homogeneous system, the relationship between partial molar and molar quantity (RPMQ) is proved to be an equivalent relation of the Gibbs-Duhem equation. The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation are inferred from the RPMQ. Based on the inference, an asymmetric regular solution model is suggested to deal with those systems that exhibit strong negative deviation, strong positive deviation, and both strong positive and negative deviation from ideality.
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