Polyoxovanadate fabricated gold nanoparticles: Application in SERS

This article reports a surface modification of gold nanoparticles with water soluble polyoxometalate, V₁₀O₂₈^6- (decavanadate, V10). Two sizes of citrate-capped gold nanoparticles AuNP-Citrate-S (∼11nm) and AuNP-Citrate-L (∼46nm) were modified with V10 in aqueous media to form AuNP-V10-S and AuNP-V10-L, respectively. Both AuNP-V10-S and AuNP-V10-L were found to be significantly better than their citrate counterparts in strengthening Raman vibrational signals of analyte molecule. All the nanoparticles were characterized by UV-visible and Fourier transform infrared (FTIR) spectroscopies, dynamic light scattering (DLS), transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) line analysis. We demonstrate that AuNP-V10-L is excellent surface-enhanced Raman scattering (SERS) substrate for a Raman-active analyte molecule at nanomolar concentrations.