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R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt), via a phosphenium intermediate
Masumi Itazaki1, Noriko Tsuchida2, Yuka Shigesato1
1Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Dalton Transactions (Cambridge, England : 2003)
|October 25, 2016
Abstract:
R/X exchange reactions in cis-[M(R)2{P(X)(NMeCH2)2}2] (M = Pd, Pt; R = aryl, alkyl; X = Cl, Br) were achieved for the first time to give cis-[M(X)2{P(R)(NMeCH2)2}2]. DFT calculations suggested that the exchange reaction proceeds via a phosphenium intermediate.
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