Phosphorescence detection of manganese(VII) based on Mn-doped ZnS quantum dots

The phosphorescent l-cysteine modified manganese-doped zinc sulfide quantum dots (l-cys-MnZnS QDs) was developed for a highly sensitive detection of permanganate anions (MnO₄^-). l-cys-MnZnS QDs, which were easily synthesized in aqueous media using safe and low-cost materials, can emit intense phosphorescence even though the solution was not deoxygenated. However, the phosphorescence of l-cys-Mn-ZnS QDs was strongly quenched by MnO₄^- ascribed to the oxidation of l-cys and the increase of surface defects on l-cys-MnZnS QDs. Under the optimal conditions, l-cys-MnZnS QDs offer high selectivity over other anions for MnO₄^- determination, and good linear Stern-Volmer equation was obtained for MnO₄^- in the range of 0.5-100μM with a detection limit down to 0.24μM. The developed method was finally applied to the detection of MnO₄^- in water samples, and the spike-recoveries fell in the range of 95-106%.