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Updated: Mar 13, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Controlled Orthogonal Self-Assembly of Heterometal-Decorated Coordination Cages
Guoliang Liu1, Matthias Zeller2, Kongzhao Su1
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 155 Yangqiao West Road, Fuzhou, Fujian, 350002, P. R. China.
Abstract:
Multiple orthogonal coordinative interactions were utilized to construct heterometal-decorated tetrahedral cages from in situ formed trinuclear ZrIV clusters through the combination with other metal ions such as CuII or PdII . Through effective use of the hard/soft acid/base principle, the orthogonal self-assembly process of Zr-bpydc-CuCl2 (H2 bpydc=2,2-bipyridine-5,5-dicarboxylic acid) can be finely controlled using three strategies: post-synthetic metallization, a stepwise metalloligand approach, or a one-pot reaction.
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