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Updated: Mar 11, 2026
Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
Published on: November 9, 2019
Metal-Free Reduction of CO2 to Methoxyborane under Ambient Conditions through Borondiformate Formation
Samaresh Chandra Sau1, Rameswar Bhattacharjee2, Pavan K Vardhanapu1
1Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, 741246, Nadia, West Bengal, India.
Abstract:
An abnormal N-heterocyclic carbene (aNHC) based homogeneous catalyst has been used for the reduction of carbon dioxide to methoxyborane in the presence of a range of hydroboranes under ambient conditions and resulted in the highest turnover number of 6000. A catalytically active reaction intermediate, [aNHC-H⋅9BBN(OCOH)2 ] was structurally characterized and authenticated by NMR spectroscopy. A detailed mechanistic cycle of this catalytic process via borondiformate formation has been proposed from tandem experimental and computational experiments.
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