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Nitrogen-Doped Mesoporous Carbon-Encapsulated MoO2 Nanobelts as a High-Capacity and Stable Host for Lithium-Ion
Xianjun Tan1, Chuanfeng Cui1, Shiqun Wu1
1Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, 200237, P. R. China.
Abstract:
N-doped mesoporous carbon-capped MoO2 nanobelts (designated as MoO2 @NC) were synthesized and applied to lithium-ion storage. Owing to the stable core-shell structural framework and conductive mesoporous carbon matrix, the as-prepared MoO2 @NC shows a high specific capacity of around 700 mA h g-1 at a current of 0.5 A g-1 , excellent cycling stability up to 100 cycles, and superior rate performance. The N-doped mesoporous carbon can greatly improve the conductivity and provide uninhibited conducting pathways for fast charge transfer and transport. Moreover, the core-shell structure improved the structural integrity, leading to a high stability during the cycling process. All of these merits make the MoO2 @NC to be a suitable and promising material for lithium ion battery.
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