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Properties of Transition Metals02:58

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Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are transition elements. The f-block elements, also called inner transition metals (the lanthanides and actinides), also meet this criterion because the d orbital is partially occupied before the f orbitals.
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A chemical symbol is an abbreviation used to indicate an element or an atom of an element. For example, the symbol for mercury is Hg. The same symbol is used to indicate one atom of mercury (microscopic domain) or to label a container of many atoms of the element mercury (macroscopic domain).
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The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
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Bulk and Thin Film Synthesis of Compositionally Variant Entropy-stabilized Oxides
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New functionalities in abundant element oxides: ubiquitous element strategy.

Hideo Hosono1, Katsuro Hayashi2, Toshio Kamiya3

  • 1Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, Japan; Secure Materials Center, Materials and Structures Laboratory, Tokyo Institute of Technology, Nagatsuta, Midori, Yokohama 226-8503, Japan; Materials and Structures Laboratory, Tokyo Institute of Technology, Nagatsuta, Midori, Yokohama 226-8503, Japan.

Science and Technology of Advanced Materials
|November 24, 2016
PubMed
Summary

This review introduces a new approach in materials science called the 'ubiquitous element strategy.' The goal is to use the ten most abundant elements in Earth's crust instead of rare ones in advanced materials. The authors analyze how these abundant elements can be used in electronic, thermionic, and structural materials. They suggest that these materials may perform as well as or better than those using rare elements. The review highlights recent research findings and proposes that this strategy could help avoid future shortages of rare elements. The authors do not claim that all rare elements can be replaced, but they suggest that this approach may be a viable alternative in many applications.

Keywords:
MgOabundant elementsaluminosilicateatomic oxygenfunctional oxidesmass spectroscopymullitenanofragmentationoxidationphase transitionpolar surfaceshock wavethin film growthzirconiaUbiquitous element strategyAbundant element materialsMaterials sustainabilityRare element crisis

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Area of Science:

  • Ceramic materials science
  • Materials sustainability research
  • Electronic materials development

Background:

Most ceramic materials are made from the ten most abundant elements in Earth's crust. However, many advanced materials rely on rare elements, creating a growing imbalance between supply and demand. This growing reliance on rare elements has raised concerns about a potential 'rare-element crisis.' Prior research has shown that the scarcity of these elements threatens the sustainability of future material innovations. No prior work had resolved how to replace rare elements in high-performance materials. That uncertainty drove the need for alternative strategies in materials design. This gap motivated the exploration of abundant elements as viable substitutes. Researchers have already identified that ceramics can be engineered with unique properties. Yet, the full potential of abundant elements in advanced applications remains underexplored.

Purpose Of The Study:

The purpose of this review is to introduce a new materials strategy focused on abundant elements. The goal is to shift material innovation from rare to ubiquitous elements. This approach aims to address the imbalance in element availability. The specific problem is the rising scarcity of rare elements in advanced materials. The motivation is to ensure long-term sustainability of material science. The review highlights how abundant elements can be used in electronic, thermionic, and structural materials. This work proposes a framework for rethinking material composition. It emphasizes the need for innovative applications of common elements.

Main Methods:

The review approach includes a synthesis of recent research findings. The authors analyze electronic, thermionic, and structural materials. They focus on materials composed of the ten most abundant elements. The strategy involves replacing rare elements with ubiquitous ones in devices. The approach is based on experimental and theoretical studies. The authors examine how these materials perform in practical applications. They compare the properties of rare-element-based and abundant-element-based materials. The synthesis includes a discussion of material design and functionality.

Main Results:

Key findings suggest that abundant elements can replace rare ones in electronic materials. For example, ceramics made from abundant elements show comparable performance. Thermionic materials using abundant elements demonstrate similar efficiency. Structural materials based on common elements maintain mechanical integrity. The review highlights that these materials can be synthesized using standard methods. Some materials even outperform their rare-element counterparts in specific applications. The findings suggest that abundant elements can be used in a wide range of devices. This approach may reduce reliance on rare elements in advanced technologies.

Conclusions:

The synthesis of findings suggests that abundant elements can be used in place of rare ones. The authors propose that this strategy may help avoid future material shortages. They suggest that electronic and structural materials can benefit from this approach. The implications include a shift in materials design toward sustainability. The review does not claim that all rare elements can be replaced. It does not propose that all applications will benefit equally. The authors suggest that further research is needed to optimize these materials. They conclude that the ubiquitous element strategy may be a viable alternative.

The authors propose a strategy to use abundant elements in place of rare ones in advanced materials.

The review suggests that ceramics made from abundant elements may perform comparably to rare-element-based materials.

The imbalance between limited supply and increasing demand threatens the sustainability of material innovations.

The review covers electronic, thermionic, and structural materials based on abundant elements.

Thermionic materials using abundant elements demonstrate similar efficiency to those using rare elements.

The authors suggest this strategy may reduce reliance on rare elements in advanced technologies.