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Related Concept Videos

P-N junction01:11

P-N junction

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A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
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Ambient Method for the Production of an Ionically Gated Carbon Nanotube Common Cathode in Tandem Organic Solar Cells
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Panchromatic Sequentially Cast Ternary Polymer Solar Cells.

Masoud Ghasemi1, Long Ye1, Qianqian Zhang2

  • 1Department of Physics and ORaCEL, North Carolina State University, Raleigh, NC, 27695, USA.

Advanced Materials (Deerfield Beach, Fla.)
|November 30, 2016
PubMed
Summary

A new sequential-casting method creates stratified bulk heterojunction solar cells by spin casting layers sequentially. This technique is ideal for polymer blends with high miscibility, simplifying solar cell fabrication.

Keywords:
mechanical alloysmiscibilitypolymer solar cellssequential castingternary blends

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Area of Science:

  • Materials Science
  • Organic Electronics
  • Photovoltaics

Background:

  • Bulk heterojunction (BHJ) solar cells are a promising photovoltaic technology.
  • Achieving stratified morphology in BHJ layers is crucial for efficient charge separation and transport.
  • Current methods for creating stratified BHJ structures can be complex, often requiring intermediate electrodes or orthogonal solvents.

Purpose of the Study:

  • To develop a simplified method for fabricating stratified bulk heterojunction (BHJ) solar cells.
  • To demonstrate the utility of this method for polymer systems prone to mechanical alloying.

Main Methods:

  • A sequential-casting ternary method was developed.
  • Two BHJ layers were spin cast sequentially.
  • The process avoided the need for a middle electrode and orthogonal solvents.

Main Results:

  • Stratified BHJ solar cells were successfully created using the sequential-casting method.
  • The method proved effective for polymers exhibiting high miscibility and forming mechanically alloyed morphologies.
  • Elimination of intermediate electrodes and orthogonal solvents simplifies the fabrication process.

Conclusions:

  • The sequential-casting ternary method offers a facile approach to fabricating stratified BHJ solar cells.
  • This method is particularly advantageous for processing polymer blends with high miscibility.
  • The developed technique has the potential to streamline the manufacturing of efficient organic solar cells.