Large area growth of vertically aligned luminescent MoS₂ nanosheets

Vertically aligned MoS₂ nanosheets (NSs) with exposed edges were successfully synthesized over a large area (∼2 cm²). The NSs were grown using an ambient pressure chemical vapor deposition technique via rapid sulfurization of sputter deposited thick molybdenum films. Extensive characterization of the grown MoS₂ NSs has been carried out using high resolution scanning and transmission electron microscopy (SEM & TEM). A special care was given to the TEM lamella preparation process by means of a focused ion beam to preserve the NS growth direction. The cross-section TEM measurements revealed the growth of densely packed, vertically aligned and straight MoS₂ NSs. Additional characterization techniques such as atomic force microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, and photoluminescence (PL) were used to evaluate the MoS₂ NSs. These studies revealed the high crystallinity and quality of the synthesized NSs. The MoS₂ NSs show visible light emission similar to mechanically exfoliated monolayer MoS₂ NSs. The striking PL signal comes from the exposed edges as shown by experimental and theoretical calculations. The vertical MoS₂ NSs also exhibit a hydrophobic character with a contact angle of 114°. The as-grown MoS₂ NSs would be highly useful in the development of catalysis, nano-optoelectronics, gas-sensing and bio-sensing device applications.