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Updated: Mar 10, 2026

Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
Proton-conducting crystalline porous materials
Xing Meng1, Hai-Ning Wang2, Shu-Yan Song3
1State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, P. R. China. songsy@ciac.ac.cn hongjie@ciac.ac.cn and College of Chemical Engineering, Shandong University of Technology, Zibo, Shandong 255049, P. R. China.
Crystalline porous materials like MOFs and COFs show promise for proton conduction. Their structures can be engineered to enhance proton mobility, leading to better proton-conducting materials.
Area of Science:
- Materials Science
- Chemistry
- Solid-State Physics
Background:
- Proton-conducting materials are crucial for energy applications.
- Crystalline porous materials offer tunable structures for proton transport.
- Existing materials face challenges in conductivity and stability.
Purpose of the Study:
- To review recent advancements in crystalline porous materials for proton conductivity.
- To highlight the structure-property relationships governing proton transport.
- To discuss the potential of MOFs, CPs, POMs, and COFs in this field.
Main Methods:
- Literature review of emerging studies on crystalline porous materials.
- Analysis of material structures and their impact on proton carrier accommodation.
- Correlation of material properties with observed proton conductivity.
Main Results:
- Crystalline porous materials exhibit unique proton conductivities.
- Designable structures and high surface areas facilitate proton carrier management.
- Understanding structure-conductivity relationships is key to material design.
Conclusions:
- Emerging crystalline porous materials show significant potential for proton conduction.
- Tailoring material structures can optimize proton carrier concentration and mobility.
- Further research will enable controllable synthesis of high-performance proton conductors.
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